Topic 5 of 7 · Statements 56–70

Quantum dynamics and symmetries

Schrödinger and von Neumann evolution, conservation laws, Wigner and Stone theorems, Kramers degeneracy and open systems.

56

Schrödinger equation

Governs the deterministic evolution of an isolated system between measurements.

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57

Unitary closed-system evolution

A self-adjoint $H$ generates unitary dynamics that preserves norm and inner products. (Time-independent $H$ shown.)

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58

Von Neumann equation

Schrödinger dynamics for density operators, including mixed states.

Dynamics ↗
59

Conserved observables

Commuting with the Hamiltonian makes an observable's whole distribution constant in time.

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60

Energy conservation

For a closed system with time-independent $H$, mean energy is conserved.

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61

Ehrenfest theorem

Expectation values follow equations resembling classical mechanics, e.g.

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62

Wigner's theorem

Symmetries preserving transition probabilities act linearly (unitary) or antilinearly (antiunitary), up to a phase.

Dynamics ↗
63

Stone's theorem

Strongly continuous one-parameter unitary groups have self-adjoint generators, justifying $H$ as the time-translation generator.

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64

Quantum Noether principle

Momentum generates translations, angular momentum rotations; symmetry of $H$ means conservation of the generator.

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65

Time reversal

Time reversal must complex-conjugate numbers, as needed for $e^{-iHt}\to e^{+iHt}$ to map consistent dynamics.

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66

Kramers degeneracy

For odd numbers of spin-1/2 particles with time-reversal symmetry, every level has a partner; magnetic fields break it.

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67

Adiabatic theorem

If the Hamiltonian changes slowly relative to the gap, a system stays in its instantaneous eigenstate.

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68

Berry phase

Cyclic adiabatic evolution gives a geometric phase beyond the dynamical phase $-\int E\,dt/\hbar$.

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69

GKSL generator

The most general generator of Markovian, completely positive, trace-preserving semigroups in finite dimension; models decoherence.

Dynamics ↗
70

Decoherence-free subspaces

If all noise operators act as the same scalar on a subspace, with Hamiltonian invariance, encoded information is immune from that noise.

Dynamics ↗

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